The browser you are using is not supported by this website. All versions of Internet Explorer are no longer supported, either by us or Microsoft (read more here: https://www.microsoft.com/en-us/microsoft-365/windows/end-of-ie-support).

Please use a modern browser to fully experience our website, such as the newest versions of Edge, Chrome, Firefox or Safari etc.

Profile photo of Ronny Berndtsson

Ronny Berndtsson

Professor, Dep Director, MECW Dep Scientific Coordinator

Profile photo of Ronny Berndtsson

Soil heterogeneity effects on acid flushing of lead-contaminated soil

Author

  • Kei Nakagawa
  • Shin-Ichiro Wada
  • Kazuro Momii Momii
  • Ronny Berndtsson

Summary, in English

A compact model for evaluation of acid flushing of heavy-metal-contaminated soil in a small-scale on-site treatment plant is proposed. The model assumes that the soil was re-packed in a container after excavation resulting in a soil structure with heterogeneous and random physical and chemical properties. To evaluate the effects of heterogeneity on the efficiency of contaminant removal by acid flushing, a numerical analysis of lead transport in the heterogeneous soil medium was performed. The model examines cation exchange and surface complexation reactions involving three cations (Ca, Pb, and H) and one anion (Cl) in both dissolved and exchangeable forms, two Pb surface complexes (SOPbCl and SOPbOH), and one Cl surface complex (SOH2Cl). The transport of these species during flushing with acid in a synthetically generated two-dimensional heterogeneous soil was simulated in the model. Results indicated that the flushing fluid preferentially followed pathways with large permeability. The heterogeneous cation exchange capacity (CEC) distribution and surface complexation sites had a significant effect on the transport of dissolved species. Because the CEC was set to a relatively low value, Pb was adsorbed mainly as surface complexes (SOPbCl and SOPbOH). Simulation results suggest that blocks of low hydraulic conductivity located in the upper part of the model domain greatly impede solute transport. Ponding conditions did not significantly affect the efficiency of decontamination. The model and its results are useful in the design of small-scale treatment plants for acid flushing.

Department/s

  • Division of Water Resources Engineering

Publishing year

2008

Language

English

Pages

121-134

Publication/Series

Environmental Modeling and Assessment

Volume

13

Document type

Journal article

Publisher

Springer

Topic

  • Water Engineering

Keywords

  • numerical simulation
  • lead-contaminated soil
  • acid flushing
  • cation exchange
  • surface complexation

Status

Published

ISBN/ISSN/Other

  • ISSN: 1573-2967